A novel O-quinodimethane strategy for an active metabolite of vitamin D3. A total synthesis of 25-hydroxy Windaus-Grundmann ketone

DOI: 10.1016/S0040-4039(00)97025-4

Source and publish data:

Tetrahedron Letters p. 6205 - 6208 (1990)

Update date:2022-08-05

Topics:

Authors:

Nemoto Nemoto

Ando Ando

Fukumoto

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Article abstract of DOI:10.1016/S0040-4039(00)97025-4

A highly diastereoselective total synthesis of 25-hydroxy Windaus-Grundmann ketone (2) was achieved via a novel regiocontrolled C-C bond formation by an intramolecular epoxide ring opening reaction of the bissulfonyl epoxide (19) as a key step, which was

Full text of DOI:10.1016/S0040-4039(00)97025-4

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