Catalytic asymmetric intramolecular hydrosilation

DOI: 10.1016/S0040-4039(00)88558-5

Source and publish data:

Tetrahedron Letters p. 7333 - 7336 (1990)

Update date:2022-07-29

Topics:

Authors:

Tamao, Kohei

Tohma, Toshihiko

Inui, Naoki

Nakayama, Osamu

Ito, Yoshihiko

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Article abstract of DOI:10.1016/S0040-4039(00)88558-5

Catalytic asymmetric intramolecular hydrosilation of di(2-propenyl)methanol in the presence of a Rh(I) complex containing (R,R)-DIOP or (R)-BINAP as ligand, followed by hydrogen peroxide oxidation, afforded optically active (2S,3R)-2,4-dimethyl-4-penume-1

Full text of DOI:10.1016/S0040-4039(00)88558-5

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