Tetrahedron Letters p. 7333 - 7336 (1990)
Update date:2022-07-29
Topics:
Tamao, Kohei
Tohma, Toshihiko
Inui, Naoki
Nakayama, Osamu
Ito, Yoshihiko
Catalytic asymmetric intramolecular hydrosilation of di(2-propenyl)methanol in the presence of a Rh(I) complex containing (R,R)-DIOP or (R)-BINAP as ligand, followed by hydrogen peroxide oxidation, afforded optically active (2S,3R)-2,4-dimethyl-4-penume-1
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