A useful Horner reagent for the synthesis of some α-methyl-α,β-unsaturated S-propyl thioesters

DOI: 10.1055/s-1991-26369

Source and publish data:

Synthesis p. 23 - 26 (1991)

Update date:2022-07-29

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Authors:

Coutrot Ph.

Charbonnier

Grison Grison

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Article abstract of DOI:10.1055/s-1991-26369

S-Alkyl 2-(dialkoxyphosphoryl)alkanethioates 3 can readily be prepared by the reaction of 2-(dialkoxyphosphoryl)alkanoyl chlorides 1 with thiols 2 in the presence of triethylamine. Only S-propyl 2-(dialkoxyphosphoryl)propanethioate (3b) gave synthetically

Full text of DOI:10.1055/s-1991-26369

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