A useful Horner reagent for the synthesis of some α-methyl-α,β-unsaturated S-propyl thioesters

DOI: 10.1055/s-1991-26369

Source and publish data:

Synthesis p. 23 - 26 (1991)

Update date:2022-07-29

Topics:

Authors:

Coutrot Ph.

Charbonnier

Grison Grison

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1991-26369

S-Alkyl 2-(dialkoxyphosphoryl)alkanethioates 3 can readily be prepared by the reaction of 2-(dialkoxyphosphoryl)alkanoyl chlorides 1 with thiols 2 in the presence of triethylamine. Only S-propyl 2-(dialkoxyphosphoryl)propanethioate (3b) gave synthetically

Full text of DOI:10.1055/s-1991-26369

Products guided by the article

Product name:2-(Diethoxy-phosphoryl)-thiopropionic acid S-p-tolyl ester

Cas No:132933-70-1

R&D Labs maybe for 132933-70-1

Zhejiang Tianyu Pharmaceutical Co., Ltd.

Contact:+86-576-84177669, 89189665,89189688,84168770

Address:Jiangkou Development Zone, Huangyan, Taizhou City, Zhejiang
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China

Relevant to this article

Exploiting domino enyne metathesis mechanisms for skeletal diversity generation

Doi:10.1039/b807278g
(2008)
Direct Synthesis of Acyl Fluorides from Carboxylic Acids with the Bench-Stable Solid Reagent (Me₄N)SCF₃

Doi:10.1021/acs.orglett.7b02516
(2017)
Enantioselective conjugate allylation of cyclic enones

Doi:10.1021/jo2013753
(2011)
NMR and molecular fluorescence spectroscopic study of the structure and thermodynamic parameters of EGCG/β-cyclodextrin inclusion complexes with potential antioxidant activity

Doi:10.1007/s10847-013-0297-y
(2014)
Unsymmetrical Disulfides Synthesis via Sulfenium Ion

Doi:10.1002/asia.201900620
(2019)
The Michael reaction of methanetricarboxylic esters. A simple method for two-carbon chain elongation

Doi:10.1055/s-1990-27111
(1990)

Article Doi