Highly Efficient Method for Epoxidation of Olefins with Molecular Oxygen and Aldehydes Catalyzed by Nickel(II) Complexes

DOI: 10.1246/cl.1991.1

Source and publish data:

Chemistry Letters p. 1 - 4 (1991)

Update date:2022-07-29

Topics:

Authors:

Yamada, Tohru

Takai, Toshihiro

Rhode, Oliver

Mukaiyama, Teruaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.1

In the presence of a catalytic amount of a bis(1,3-diketonato)nickel(II) complex, trisubstituted and exo-terminal olefins or norbornene analogues are smoothly monooxygenated into the corresponding epoxides in high to quantitative yields on treatment with aldehyde under an atmospheric pressure of oxygen at room temperature.

Full text of DOI:10.1246/cl.1991.1

Products guided by the article

Product name:Oxirane, 2-(4-fluorophenyl)-3-pentyl-, (2R,3R)-rel-

Cas No:132934-79-3

R&D Labs maybe for 132934-79-3

Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Jinan Hongfangde Pharmatech Co.LTD

Contact:0531-88870908

Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549

Relevant to this article

Synthesis and bioactivity of propranolol analogues with a rigid skeleton. I

Doi:10.1248/cpb.38.3257
(1990)
Metal-free asymmetric 1,3-dipolar cycloaddition of N-arylmaleimides to azomethine ylides catalyzed by chiral tertiary amine thiourea

Doi:10.1002/ejoc.201100205
(2011)
Synthesis of three-dimensionally arranged bis-biphenol ligand on hexaaryl benzene scaffold and its application for cross-pinacol coupling reaction

Doi:10.1016/j.tetlet.2011.06.113
(2011)
Kinetic resolution of β-lactams via enantioselective N-acylation

Doi:10.1021/ol201911z
(2011)
Efficient synthesis of hydroxylated polyethylene via copolymerization of ethylene with 5-norbornene-2-methanol using bis(β-enaminoketonato)titanium catalysts

Doi:10.1021/om200526n
(2011)
Formation of 1,2-dioxacyclohexanes by the reaction of alkenes with tris(2,4-pentanedionato)manganese(III) or with β-ketocarbonyl compounds in the presence of manganese(III) acetate

Doi:10.1016/S0040-4039(00)97067-9
(1990)

Article Doi