Highly Efficient Method for Epoxidation of Olefins with Molecular Oxygen and Aldehydes Catalyzed by Nickel(II) Complexes

DOI: 10.1246/cl.1991.1

Source and publish data:

Chemistry Letters p. 1 - 4 (1991)

Update date:2022-07-29

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Authors:

Yamada, Tohru

Takai, Toshihiro

Rhode, Oliver

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1991.1

In the presence of a catalytic amount of a bis(1,3-diketonato)nickel(II) complex, trisubstituted and exo-terminal olefins or norbornene analogues are smoothly monooxygenated into the corresponding epoxides in high to quantitative yields on treatment with aldehyde under an atmospheric pressure of oxygen at room temperature.

Full text of DOI:10.1246/cl.1991.1

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