Journal of the Chemical Society, Dalton Transactions p. 4149 - 4150 (1996)
Update date:2022-07-30
Topics:
Cross, Ronald J.
Farrugia, Louis J.
Newman, Paul D.
Peacock, Robert D.
Stirling, Diane
Homochiral hydroxyphosphoryl compounds, L, such as the novel camphor-based (1R)-endo,endo-3S-(diphenylphosphoryl)-2R-hydroxybornane, have been found to be prevented from behaving as bidentate ligands in the epoxidation catalysts [MoO(O2)2L(H2O)] by unexpectedly strong multiple-bond delocalisation producing near linear Mo-O-P angles.
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