Enantioselective aldol reaction using bornane-2,3-diol-aluminum complex as a chiral Lewis acid

DOI: 10.1055/s-1997-6148

Source and publish data:

Synlett p. 501 - 502 (1997)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Makoto

Kawamoto, Manabu

Yamamoto, Yasushi

Fujisawa, Tamotsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-6148

β-Hydroxy ester was formed in high enantiomeric excess by the reaction of ketene silyl acetal with aldehyde in the presence of a chiral Lewis acid prepared from diethylaluminum chloride and chiral diol derived from (+)-camphor.

Full text of DOI:10.1055/s-1997-6148

Products guided by the article

Product name:(R)-3-Hydroxy-2,2-dimethyl-5-phenyl-pentanoic acid ethyl ester

Cas No:133270-75-4

R&D Labs maybe for 133270-75-4

SuZhou Yacoo Science Co., Ltd

Contact:86-512-87182055

Address:No.128 Fangzhou Rd, Suzhou Industrial Park, China, 215125, China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China

Relevant to this article

Selectivity in reduction of natural furanoheliangolides with Stryker's reagent

Doi:10.1039/c1ob05734k
(2011)
Emissive RNA alphabet

Doi:10.1021/ja206095a
(2011)
Synthesis and structure-activity relationships of varied ether linker analogues of the antitubercular drug (6 S)-2-nitro-6-{[4-(trifluoromethoxy) benzyl]oxy}-6,7-dihydro-5 H -imidazo[2,1- b ][1,3]oxazine (PA-824)

Doi:10.1021/jm200377r
(2011)
A near-infrared reversible fluorescent probe for peroxynitrite and imaging of redox cycles in living cells

Doi:10.1039/c1cc12994e
(2011)
Single step synthesis of strigolactone analogues from cyclic keto enols, germination stimulants for seeds of parasitic weeds

Doi:10.1016/j.bmc.2011.06.057
(2011)
Identification of pyridazin-3-one derivatives as potent, selective histamine H₃ receptor inverse agonists with robust wake activity

Doi:10.1016/j.bmcl.2011.06.108
(2011)

Article Doi