Enantioselective aldol reaction using bornane-2,3-diol-aluminum complex as a chiral Lewis acid

DOI: 10.1055/s-1997-6148

Source and publish data:

Synlett p. 501 - 502 (1997)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Makoto

Kawamoto, Manabu

Yamamoto, Yasushi

Fujisawa, Tamotsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-6148

β-Hydroxy ester was formed in high enantiomeric excess by the reaction of ketene silyl acetal with aldehyde in the presence of a chiral Lewis acid prepared from diethylaluminum chloride and chiral diol derived from (+)-camphor.

Full text of DOI:10.1055/s-1997-6148

Products guided by the article

Product name:(R)-3-Hydroxy-2,2-dimethyl-5-phenyl-pentanoic acid ethyl ester

Cas No:133270-75-4

R&D Labs maybe for 133270-75-4

Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province

Relevant to this article

Selectivity in reduction of natural furanoheliangolides with Stryker's reagent

Doi:10.1039/c1ob05734k
(2011)
Emissive RNA alphabet

Doi:10.1021/ja206095a
(2011)
Synthesis and structure-activity relationships of varied ether linker analogues of the antitubercular drug (6 S)-2-nitro-6-{[4-(trifluoromethoxy) benzyl]oxy}-6,7-dihydro-5 H -imidazo[2,1- b ][1,3]oxazine (PA-824)

Doi:10.1021/jm200377r
(2011)
A near-infrared reversible fluorescent probe for peroxynitrite and imaging of redox cycles in living cells

Doi:10.1039/c1cc12994e
(2011)
Single step synthesis of strigolactone analogues from cyclic keto enols, germination stimulants for seeds of parasitic weeds

Doi:10.1016/j.bmc.2011.06.057
(2011)
Identification of pyridazin-3-one derivatives as potent, selective histamine H₃ receptor inverse agonists with robust wake activity

Doi:10.1016/j.bmcl.2011.06.108
(2011)

Article Doi