Enantioselective aldol reaction using bornane-2,3-diol-aluminum complex as a chiral Lewis acid

DOI: 10.1055/s-1997-6148

Source and publish data:

Synlett p. 501 - 502 (1997)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Makoto

Kawamoto, Manabu

Yamamoto, Yasushi

Fujisawa, Tamotsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-6148

β-Hydroxy ester was formed in high enantiomeric excess by the reaction of ketene silyl acetal with aldehyde in the presence of a chiral Lewis acid prepared from diethylaluminum chloride and chiral diol derived from (+)-camphor.

Full text of DOI:10.1055/s-1997-6148

Products guided by the article

Product name:(R)-3-Hydroxy-2,2-dimethyl-5-phenyl-pentanoic acid ethyl ester

Cas No:133270-75-4

R&D Labs maybe for 133270-75-4

Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Henan Techway Chemical Co.,Ltd.

website:http://www.techwaychem.com

Contact:+86-371-66380080

Address:No.27 Shunhe Road,
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China

Relevant to this article

Selectivity in reduction of natural furanoheliangolides with Stryker's reagent

Doi:10.1039/c1ob05734k
(2011)
Emissive RNA alphabet

Doi:10.1021/ja206095a
(2011)
Synthesis and structure-activity relationships of varied ether linker analogues of the antitubercular drug (6 S)-2-nitro-6-{[4-(trifluoromethoxy) benzyl]oxy}-6,7-dihydro-5 H -imidazo[2,1- b ][1,3]oxazine (PA-824)

Doi:10.1021/jm200377r
(2011)
A near-infrared reversible fluorescent probe for peroxynitrite and imaging of redox cycles in living cells

Doi:10.1039/c1cc12994e
(2011)
Single step synthesis of strigolactone analogues from cyclic keto enols, germination stimulants for seeds of parasitic weeds

Doi:10.1016/j.bmc.2011.06.057
(2011)
Identification of pyridazin-3-one derivatives as potent, selective histamine H₃ receptor inverse agonists with robust wake activity

Doi:10.1016/j.bmcl.2011.06.108
(2011)

Article Doi