TOTAL SYNTHESIS OF (11R,12S)-diHETE

DOI: 10.1016/S0040-4039(00)74847-7

Source and publish data:

Tetrahedron Letters p. 635 - 638 (1991)

Update date:2022-07-29

Topics:

Authors:

Gigou, Agnes

Beaucourt, Jean-Pierre

Lellouche, Jean-Paul

Gree, Rene

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Article abstract of DOI:10.1016/S0040-4039(00)74847-7

The first total synthesis of (11R,12S) diHETE is reported.The key step is the highly chemio- and stereoselective osmylation of a double bond in a trienyne system selectively complexed by an Fe(CO)3 group.

Full text of DOI:10.1016/S0040-4039(00)74847-7

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