Synthesis of new chiral catalysts, N-alkyl-2-azanorbornyl-methanols, for the enantioselective addition of diethylzinc to arylaldehydes

DOI: 10.1016/0957-4166(95)00151-E

Source and publish data:

Tetrahedron Asymmetry p. 1233 - 1236 (1995)

Update date:2022-08-03

Topics:

Authors:

Nakano Nakano

Kumagai Kumagai

Kabuto Kabuto

Matsuzaki

Hongo Hongo

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Article abstract of DOI:10.1016/0957-4166(95)00151-E

New chiral ligands, 2-azanorbornylmethanols, were prepared and catalyzed the addition of diethylzinc to arylaldehydes to furnish secondary alcohols in up to 92% ee.

Full text of DOI:10.1016/0957-4166(95)00151-E

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Product name:(1R,3S,4S)-2-<(R)-1-phenylethyl>-2-azabicyclo<2.2.1>heptane-3-exo-methanol

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