Tetrahedron Letters p. 1171 - 1174 (1991)
Update date:2022-09-26
Topics: Asymmetric synthesis Alkylation Diastereoselectivity Chiral Hydrazone Templates
Alexakis, Alexandre
Lensen, Nathalie
Mangeney, Pierre
Glyoxal is efficiently transformed into the chiral aminals bearing the hydrazone functionality 2a and 2b.These compounds react under complete diastereocontrol with various organolithium reagents, affording chiral hydrazines 3-9.Reduction with Raney nickel
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Doi:10.1007/BF00959665
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