SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF SILYL NITRONATES (SILYL ESTERS OF ACI-NITROALKANES): TOWARDS THE SN2 REACTION PATH WITH RETENTION OF CONFIGURATION AT SILICON

DOI: 10.1002/hlca.19800630320

Source and publish data:

Helvetica Chimica Acta p. 697 - 710 (1980)

Update date:2022-09-26

Topics:

Authors:

Colvin, Ernest W.

Beck, Albert K.

Bastani, Bahram

Seebach, Dieter

Kai, Yasushi

Dunitz, Jack D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19800630320

An efficient and flexible method for the preparation of silyl nitronates is described (see 1-10).NMR. spectral investigations indicate a rapid 1,3-silyl migration process, with an activation energy of about 10 kcal mol^-1.X-ray crystallographic

Full text of DOI:10.1002/hlca.19800630320

Products guided by the article

Product name:tert-butyldimethylsilyl (phenylmethylene)azinate

Cas No:133683-75-7

R&D Labs maybe for 133683-75-7

Deltachem(QingDao)Co.,Ltd.

Contact:+8618766299236

Address:ROOM808, BUILDING2,NO.230 SHEN ZHEN ROAD, LAOSHAN DISTRICT
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Taizhou Crene Biotechnology co.ltd

Contact:86-576-88813233 88205808

Address:Economic Developed Zone of Taizhou Zhejiang China
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu

Relevant to this article

Synthesis of chiral disulfides: Potential reagents for enantioselective sulfurization

Doi:10.1080/17415993.2011.580346
(2011)
Synthesis and biological activity of desmethoxy analogues of coruscanone A

Doi:10.1016/j.bmcl.2011.08.059
(2011)
Ionic liquid-accelerated allylation of carbonyl compounds with a catalytic amount of indium generated from in Situ reduction of InCl₃ with aluminum

Doi:10.1246/cl.2011.506
(2011)
A dual-catalysis approach to the asymmetric steglich rearrangement and catalytic enantioselective addition of O-acylated azlactones to isoquinolines

Doi:10.1021/ja208156z
(2011)
Oxo/imido heterometathesis of N-sulfinylamines and carbonyl compounds catalyzed by silica-supported vanadium oxochloride

Doi:10.1016/j.jcat.2011.07.011
(2011)
Microwave assisted copper-free Sonogashira coupling/5-exo-dig cycloisomerization domino reaction: Access to 3-(phenylmethylene)isoindolin-1- ones and related heterocycles

Doi:10.1016/j.tetlet.2011.08.070
(2011)

Article Doi