Diastereoselectivity in Nucleophilic Addition Reactions to (α,β-Dialkoxyacyl)silanes: An Operationally Useful Route to Optically Active 1,2,3-syn-Triols

DOI: 10.1021/jo00312a005

Source and publish data:

Journal of Organic Chemistry p. 6071 - 6073 (1990)

Update date:2022-08-04

Topics:

Authors:

Cirillo, Pier F.

Panek, James S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00312a005

silanes 3 undergo chelation-controlled nucleophilic addition reactions to produce Cram-type addition products (1,2,3-syn-triol derivatives) 4 with useful levels of diastereoselectivity.

Full text of DOI:10.1021/jo00312a005

Products guided by the article

Product name:(2R,3S,4S)-3-Benzyloxymethoxy-hept-6-ene-2,4-diol

Cas No:133775-94-7

R&D Labs maybe for 133775-94-7

Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area

Relevant to this article

PHENOLIC CONSTITUENTS OF PHELLODENDRON AMURENSE BARK

Doi:10.1016/S0031-9422(00)90536-3
(1994)
Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex

Doi:10.1021/jacs.7b03433
(2017)
Doi:10.1021/ja01328a503
(1933)
Benzopyrans are selective estrogen receptor β agonists with novel activity in models of benign prostatic hyperplasia

Doi:10.1021/jm060491j
(2006)
Radical-induced formation of some siloles and diazasiloles

Doi:10.1021/jo0202684
(2002)
Doi:10.1021/ja01233a002
()

Article Doi