Diastereoselectivity in Nucleophilic Addition Reactions to (α,β-Dialkoxyacyl)silanes: An Operationally Useful Route to Optically Active 1,2,3-syn-Triols

DOI: 10.1021/jo00312a005

Source and publish data:

Journal of Organic Chemistry p. 6071 - 6073 (1990)

Update date:2022-08-04

Topics:

Authors:

Cirillo, Pier F.

Panek, James S.

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Article abstract of DOI:10.1021/jo00312a005

silanes 3 undergo chelation-controlled nucleophilic addition reactions to produce Cram-type addition products (1,2,3-syn-triol derivatives) 4 with useful levels of diastereoselectivity.

Full text of DOI:10.1021/jo00312a005

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