Diastereoselectivity in Nucleophilic Addition Reactions to (α,β-Dialkoxyacyl)silanes: An Operationally Useful Route to Optically Active 1,2,3-syn-Triols

DOI: 10.1021/jo00312a005

Source and publish data:

Journal of Organic Chemistry p. 6071 - 6073 (1990)

Update date:2022-08-04

Topics:

Authors:

Cirillo, Pier F.

Panek, James S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00312a005

silanes 3 undergo chelation-controlled nucleophilic addition reactions to produce Cram-type addition products (1,2,3-syn-triol derivatives) 4 with useful levels of diastereoselectivity.

Full text of DOI:10.1021/jo00312a005

Products guided by the article

Product name:(2R,3S,4S)-3-Benzyloxymethoxy-hept-6-ene-2,4-diol

Cas No:133775-94-7

R&D Labs maybe for 133775-94-7

Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Hangzhou Zhenghan Biological Technology Co., Ltd.

Contact:86-571-88781753

Address:liangzhu yuhang hangzhou city
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park

Relevant to this article

PHENOLIC CONSTITUENTS OF PHELLODENDRON AMURENSE BARK

Doi:10.1016/S0031-9422(00)90536-3
(1994)
Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex

Doi:10.1021/jacs.7b03433
(2017)
Doi:10.1021/ja01328a503
(1933)
Benzopyrans are selective estrogen receptor β agonists with novel activity in models of benign prostatic hyperplasia

Doi:10.1021/jm060491j
(2006)
Radical-induced formation of some siloles and diazasiloles

Doi:10.1021/jo0202684
(2002)
Doi:10.1021/ja01233a002
()

Article Doi