Highly Regio- and Stereocontrolled Glyoxylate-Ene Reaction with (Homo)Allylic Ethers: Remarkable Alkoxy Effect in Regio- and Stereocontrol

DOI: 10.1021/jo00009a003

Source and publish data:

Journal of Organic Chemistry p. 2952 - 2953 (1991)

Update date:2022-08-05

Topics:

Authors:

Mikami, Koichi

Shimizu, Masaki

Nakai, Takeshi

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Article abstract of DOI:10.1021/jo00009a003

A highly regio- and stereocontrolled glyoxylate-ene reaction with allylic and homoallylic ethers has been developed, which allows regio- and stereospecific multifunctionalizations as highlighted by a short synthesis of (+/-)-avenaciolide.

Full text of DOI:10.1021/jo00009a003

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