A novel synthetic route to 1-aza-2-silacyclopentane derivatives

DOI: 10.1016/0022-328X(91)83173-2

Source and publish data:

Journal of Organometallic Chemistry p. 87 - 89 (1991)

Update date:2022-08-03

Topics:

Authors:

Voronkov, M. G.

Kirpichenko, S. V.

Abrosimova, A. T.

Albanov, A. I.

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Article abstract of DOI:10.1016/0022-328X(91)83173-2

Me2HSiCH2CH2CH2Cl reacts with primary alkyl, aryl or aralkyl amines to form the corresponding 1-aza-2-silacyclopentanes Me2R.It seems that the ease of ring closure is a result of enhanced reactivity of the Si-H bond of the intermediate arising from intramolecular Si...N interaction.

Full text of DOI:10.1016/0022-328X(91)83173-2

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