New Stable Dication of 1,3,4,6-Tetrakis(isopropylthio)-2λ4,δ2-thienothiophene generated by its Oxidation using Nitrosonium Tetrafluoroborate

DOI: 10.1039/c39910000520

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 520 - 521 (1991)

Update date:2022-07-30

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Authors:

Tsubouchi, Akira

Matsumura, Noboru

Inoue, Hiroo

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Article abstract of DOI:10.1039/c39910000520

The oxidation of 1,3,4,6-tetrakis(isopropylthio)-2λ⁴,δ²-thieno<3,4-c>thiophene 1 by NOBF4 (2 equiv.) gives the dication 2, which reacts with H2O, MeOH and aniline to give the thiophene derivatives 3-5 by fission of the C-S bond of th

Full text of DOI:10.1039/c39910000520

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