Organic Synthesis Utilizing Beckmann Fragmentation: New Carbon-Carbon Bond Formation by the Reaction of α-Alkoxycycloalkanone Oxime Acetates with Organoaluminium Reagents

DOI: 10.1039/c39910000533

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Journal of the Chemical Society. Chemical communications p. 533 - 534 (1991)

Update date:2022-08-03

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Authors:

Fujioka, Hiromichi

Yamanaka, Takeshi

Takuma, Kazuhiro

Miyazaki, Makoto

Kita, Yasuyuki

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Article abstract of DOI:10.1039/c39910000533

The reaction of α-alkoxycycloalkanone oxime acetates 1 with organoaluminium reagents caused Beckmann fragmentation and subsequent carbon-carbon bond formation to give various types of ω-cyano-α-alkyl (or alkynyl)ethers 2 in high yields.

Full text of DOI:10.1039/c39910000533

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