A Facile Synthesis of Bicycloalkan-1-ols. Evidence for Organosamarium Intermediates in the Samarium(II) Iodide Promoted Intramolecular Barbier-Type Reaction

DOI: 10.1021/jo00013a008

Source and publish data:

Journal of Organic Chemistry p. 4112 - 4120 (1991)

Update date:2022-09-26

Topics: Facile Synthesis Samarium(II) iodide

Authors:

Molander, Gary A.

McKie, Jeffrey A.

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Article abstract of DOI:10.1021/jo00013a008

Samarium(II) iodide (SmI2) has been successfully employed as a reductive coupling agent for the intramolecular Barbier-type synthesis of bicycloalkan-1-ols.Thus, a variety of 3-(ω-iodoalkyl)cycloalkanones, upon treatment with SmI2 and a catalytic q

Full text of DOI:10.1021/jo00013a008

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