Journal of Organic Chemistry p. 4601 - 4602 (1991)
Update date:2022-09-26
Topics:
Feldman, Ken S.
Burns, Christopher J.
The cyclopentabenzofuran ring system of the antileukemic natural product rocaglamide can be efficiently prepared by intramolecular <3+2> radical mediated addition.The sterochemical relationship that emerges between C(2) and C(3) upon cyclization is identical with that seen in the natural product.
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