Tetrahedron Letters p. 1199 - 1202 (1991)
Update date:2022-08-04
Topics:
Fuchikami, Takamasa
Ubukata, Yumiko
Tanaka, Yasutaka
Group 6 anionic ·-hydride complexes catalyze hydrogenation of conjugated olefins, aldehydes, ketoesters, and alkynes, and hydrosilylation of aldehydes and conjugated olefins with high regio- and stereoselectivity. Ketones are converted into silyl ethers and silyl enol ethers with monohydrosilanes and dihydrosilanes, respectively.
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