Tetrahedron Letters p. 1583 - 1586 (1991)
Update date:2022-07-30
Topics:
Nativi, Cristina
Palio, Giovanni
Taddei, Maurizio
The presence of a stereocenter close to the double bond of an allylsilane has an influence on the stereochemistry of the reaction with electrophiles.The stereoselectivity follows the rule of electrophilic attack on a trigonal carbon adjacent to a stereogenic center proposed by Houk.From chiral allylsilanes and achiral aldehydes it is possible to prepare homo allyl alcohols with three stereocenters with a good stereoselectivity.
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