First Example of Direct Carbon Dioxide Incorporation into 1,3-Diynes: A Highly Regio- and Stereo-selective Nickel-catalysed Electrochemical Reaction

DOI: 10.1039/c39910000549

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 549 - 550 (1991)

Update date:2022-08-03

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Authors:

Derien, Sylvie

Clinet, Jean-Claude

Dunach, Elisabet

Perichon, Jacques

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Article abstract of DOI:10.1039/c39910000549

The electrosynthesis of 2-vinylidene-3-yne carboxylic acids from carbon dioxide and substituted 1,3-diynes is catalysed by a nickel-triamine complex and results in a regio- and stereo-selective addition to one triple bond.

Full text of DOI:10.1039/c39910000549

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