Enantioselective Darzens reaction: Asymmetric synthesis of trans-glycidic esters mediated by chiral lithium amides

DOI: 10.1248/cpb.43.1821

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1821 - 1823 (1995)

Update date:2022-08-04

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Authors:

Takahashi

Muraoka Muraoka

Capo Capo

Koga Koga

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Article abstract of DOI:10.1248/cpb.43.1821

Enantioselective and diastereoselective Darzens reaction mediated by chiral lithium amides was achieved between tert-butyl chloroacetate and aromatic aldehydes to give the corresponding trans-glycidic esters in up to 84% enantiomeric excess.

Full text of DOI:10.1248/cpb.43.1821

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