Journal of the Chemical Society. Chemical communications p. 574 - 577 (1991)
Update date:2022-08-04
Topics:
Bonar-Law, Richard P.
Sanders, Jeremy K. M.
A porphyrin capped with a steroidal superstructure bearing convergent hydroxy groups has been synthesized and shown to bind a variety of functionalized amines via a combination of metal-amine and hydrogen-bonding interactions; the metal-ligand interaction was used to catalyse and control selective acylation of a single hydroxy group in the cap.
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