Investigation of a Model for 1,2-Asymmetric Induction in Reactions of α-Carbalkoxy Radicals: A Stereochemical Comparison of Reactions of α-Carbalkoxy Radicals and Ester Enolates

DOI: 10.1021/jo00042a029

Source and publish data:

Journal of Organic Chemistry p. 4457 - 4470 (1992)

Update date:2022-08-04

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Authors:

Hart, David J.

Krishnamurthy, Ramanarayanan

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Article abstract of DOI:10.1021/jo00042a029

The stereochemical course of reductions and allylations of α-carbalkoxy radicals with chiral centers at the β-position are reported.Radicals without polar substituents, with alkoxyl or acetoxyl groups, and with hydroxyl groups at the β-position were exami

Full text of DOI:10.1021/jo00042a029

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