Investigation of a Model for 1,2-Asymmetric Induction in Reactions of α-Carbalkoxy Radicals: A Stereochemical Comparison of Reactions of α-Carbalkoxy Radicals and Ester Enolates

DOI: 10.1021/jo00042a029

Source and publish data:

Journal of Organic Chemistry p. 4457 - 4470 (1992)

Update date:2022-08-04

Topics:

Authors:

Hart, David J.

Krishnamurthy, Ramanarayanan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00042a029

The stereochemical course of reductions and allylations of α-carbalkoxy radicals with chiral centers at the β-position are reported.Radicals without polar substituents, with alkoxyl or acetoxyl groups, and with hydroxyl groups at the β-position were exami

Full text of DOI:10.1021/jo00042a029

Products guided by the article

Product name:rel-(20S)-ethyl 3β-(tert-butyldimethylsiloxy)-20-(phenylselenenyl)pregn-5-en-21-oate

Cas No:135215-54-2

R&D Labs maybe for 135215-54-2

Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.

Relevant to this article

7-Deazapurine and 8-aza-7-deazapurine nucleoside and oligonucleotide pyrene "click" conjugates: Synthesis, nucleobase controlled fluorescence quenching, and duplex stability

Doi:10.1021/jo202103q
(2012)
Magnesium, zinc and aluminium complexes supported by tripodal diaminebis(aryloxido) ligands: Synthesis, solid state and solution structure

Doi:10.1039/c3dt50938a
(2013)
5,15-A₂B₂- and 5,15-A₂BC-type porphyrins with donor and acceptor groups for use in nonlinear optics and photodynamic therapy

Doi:10.1002/ejoc.201100641
(2011)
Heterotrinuclear complexes with palladium, rhodium, and iridium ions assembled by conformational switching of a tetraphosphine ligand around a palladium center

Doi:10.1021/om2006744
(2012)
Chemoselective activation of trimethylsilyl enol ether functionalities in the presence of silyl-protected alcohols by trimethylsilyl-nonaflyl exchange

Doi:10.1055/s-0030-1260207
(2011)
Study on molecular and electronic structures, and spectroscopic properties of azide ruthenium complexes with pyridine and β-picoline ligands

Doi:10.1016/j.poly.2011.08.043
(2012)

Article Doi