Asymmetricsynthesis. XXXII. Formalsynthesisof (-) - Perhydrohistrionicotoxin

DOI: 10.1016/S0040-4039(00)74361-9

Source and publish data:

Tetrahedron Letters p. 2485 - 2488 (1991)

Update date:2022-09-26

Topics:

Authors:

Zhu, Jieping

Royer, Jacques

Quirion, Jean-Charles

Husson, Henri-Phillippe

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Article abstract of DOI:10.1016/S0040-4039(00)74361-9

The synthesis of (-)-depentylperhydrohistrionicotoxin 2 from the 2-cyano-6-oxazolopiperidine synthon (-) 3 has been achieved. The spiro skeleton was formed by an aldol cyclization of a methyl ketone and an aldehyde function belonging to chains borne at C-

Full text of DOI:10.1016/S0040-4039(00)74361-9

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