Novel reaction of selenobenzophenones with alkyllithiums leading to symmetrical olefins

DOI: 10.1246/cl.1996.609

Source and publish data:

Chemistry Letters p. 609 - 610 (1996)

Update date:2022-07-29

Topics:

Authors:

Okuma, Kentaro

Koda, Gen

Okumura, Seiji

Ohno, Atsuyoshi

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Article abstract of DOI:10.1246/cl.1996.609

The reaction of selenobenzophenones with alkyllithiums or Grignard Reagents exclusively affords symmetrical tetraarylethylenes as selenophilic products. The reaction might proceed through episelenide (selenirane) intermediates.

Full text of DOI:10.1246/cl.1996.609

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