Journal of Organic Chemistry p. 5834 - 5845 (1991)
Update date:2022-09-26
Topics: Stereospecific synthesis Rapamycin
Chen, Sui-Hui
Horvath, Raymond F.
Joglar, Jesus
Fisher, Matthew J.
Danishefsky, Samuel J.
The aldehydes 49 and 55 corresponding to carbons 13-30 in a projected total synthesis of rapamycin have been synthesized.The LACDAC technology was used to elaborate dithiane enal 5.The aldehyde 4 was synthesized from D-(+)-glucose.A critical element of th
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