Journal of the American Chemical Society p. 2547 - 2550 (2012)
Update date:2022-07-30
Topics:
Michaudel, Quentin
Thevenet, Damien
Baran, Phil S.
Intermolecular Ritter-type C-H amination of unactivated sp3 carbons has been developed. This new reaction proceeds under mild conditions using readily available reagents and an inexpensive source of nitrogen (acetonitrile). A broad scope of substrates can be aminated with this method since many functional groups are tolerated. This reaction also allows for the direct, innate C-H amination of a variety of hydrocarbons such as cyclohexane without the need of prefunctionalization or installation of a directing group.
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