Organometallics p. 3389 - 3392 (1991)
Update date:2022-09-26
Topics:
Bryson
Youinou
Osborn
The motybdenum(VI) complex (AR′N)2MoCl2· THF (Ar′ = 2,6-diisopropylphenyl) was prepared by reaction of MoO2Cl2 with Ar′NCO at 70°C in THF. The preparations of the derivatives Mo(NAr′)2Np2, Mo-(NAr′)2Mes2, Mo(NAr′)2MeSBr. Mo(NAr′)2(NEt2)Cl, and Mo-(NAr′)2(NEt2)2 from Mo(NAK)2Cl2-THF are described. In addition, the complex Mo(NAr′)2(NHAK)2 has been synthesized and characterized crystallographically. Crystal data: MoC48H70N4, Mr = 799.06, monoclinic, P21/n, a = 9.874 (3) A?, b = 24.004 (8) A?, c = 19.220 (7) A?, β = 93.34 (2) A?, V = 4547 A?3, Z = 4, ρcalc = 1.167 g cm-3, λ = 1.5418 A?, μ = 26.35 cm-1, T = -100°C, R = 4.22% for 4426 unique observed [I ≥ 3σ(I)] reflections, Rw = 7.65%.
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Doi:10.1021/jo00297a075
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(2011)
