Areneselenolate-mediated perfluoroalkyl-sulfenylation of enol ethers

DOI: 10.1016/S0040-4039(00)92713-8

Source and publish data:

Tetrahedron Letters p. 3385 - 3386 (1991)

Update date:2022-07-30

Topics: Regioselectivity Column chromatography Yield Catalyst Nucleophile Electrophile Solvent TLC (thin-layer chromatography) NMR (nuclear magnetic resonance) Anhydrous conditions Reaction Mechanism Stereoselectivity Enol Ethers Oxidation state Radical intermediate Inert atmosphere GC-MS (Gas Chromatography-Mass Spectrometry)

Authors:

Uneyama, Kenji

Kitagawa, Kouichi

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Article abstract of DOI:10.1016/S0040-4039(00)92713-8

Areneselenolate-mediated perfluoroalkyl-sulfenylation of enol ethers has been performed by the reaction of sodium arenethiolates, a catalytic amount of sodium areneselenolates, perfluoroalkyl iodides, and olefins where ArSeNa initiates a chain reaction vi

Full text of DOI:10.1016/S0040-4039(00)92713-8

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