Enantiomerically pure vinylketene acetals in the Diels-Alder reaction. Catalysis and facial selectivity

DOI: 10.1016/S0040-4020(01)86459-0

Source and publish data:

Tetrahedron p. 4519 - 4538 (1991)

Update date:2022-07-29

Topics:

Authors:

Boehler Boehler

Konopelski

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Article abstract of DOI:10.1016/S0040-4020(01)86459-0

A series of enantiomerically pure vinylketene acetals which function as diastereoselective dienes in the Diels-Alder reaction have been developed. Most selective are (4R, 5R)-4,5-diphenyl-2-(2-methyl-2-propenidene)-1,3-dioxolane (8) and (4R, 5R)-4,5-diphe

Full text of DOI:10.1016/S0040-4020(01)86459-0

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