STEREOSELECTIVE SYNTHESES OF DI-, TRI-, AND TETRASUBSTITUTED ENEDIYNES FROM ENYNYL IODIDES VIA Pd-CATALYZED COUPLING REACTIONS

DOI: 10.1016/S0040-4039(00)92698-4

Source and publish data:

Tetrahedron Letters p. 3329 - 3332 (1991)

Update date:2022-08-03

Topics:

Authors:

Stracker, Elaine C.

Zweifel, George

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Article abstract of DOI:10.1016/S0040-4039(00)92698-4

Palladium catalyzed cross-coupling of iodoenynes derived from mono(stannyl)enynes with alkynyl zinc reagents affords isomerically pure conjugated di-, tri- and tetrasubstituted (Z)-enedines and trisubstituted cross-conjugated enediynes in high yields.

Full text of DOI:10.1016/S0040-4039(00)92698-4

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Product name:(Z)-1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-4-trimethylsilanylethynyl-dec-3-en-1-yne

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