Enantioselective Synthesis of Nitrogen Derivatives by Allyl Grignard Addition on Optically Active Nitroalkanes

DOI: 10.1039/c39910000793

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 793 - 794 (1991)

Update date:2022-08-03

Topics:

Authors:

Bartoli, Giuseppe

Marcantoni, Enrico

Petrini, Marino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000793

Reaction of optically active nitroalkanes with allyl Grignard reagents affords E-Z mixtures of nitrones which can be reduced to chiral hydroxylamines and amines.

Full text of DOI:10.1039/c39910000793

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-((S)-2-Benzyloxy-propyl)-N-((S)-1-ethyl-allyl)-hydroxylamine

Cas No:136113-20-7

R&D Labs maybe for 136113-20-7

Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China

Relevant to this article

Lithium Cation-Catalyzed Wittig Reactions

Doi:10.1021/jo00084a034
(1994)
Low-energy ion-surface reactions of pyrazine with two classes of self- assembled monolayers: Influence of alkyl chain orientation

Doi:10.1021/ac0001028
(2000)
Selective reactions of functionalized ruthenium(II) σ-alkynyl complexes with dicobalt octacarbonyl and tetracobalt dodecacarbonyl: Synthesis of cyclopentenone derivatives via intermolecular pauson-khand reactions

Doi:10.1021/om970645g
(1998)
Syntheses of the complete set of isomerically pure, partially fluorinated cyclopentadienyl ligands (C₅F_5-nH_n) [n = 1-4] by flash vacuum thermolysis of (η⁵-Oxocyclohexadienyl)ruthenium complexes. Molecular structures of [Ru(η⁵-C₅Me₅) (η⁵-C₅-1,2-F₂H₃)]

Doi:10.1021/om970775p
(1998)
Studies on lactams. X. Total synthesis of 5,6-trans-penicillin V methyl ester.

Doi:10.1021/ja01018a087
(1968)
Unusual regioselectivity in the reductive coupling of alkynes and allenes by hydrozirconation and zinca-claisen rearrangement

Doi:10.1002/anie.199724691
(1997)

Article Doi