Tetrahedron Letters p. 4835 - 4838 (1992)
Update date:2022-08-03
Topics: Oxidation Oxime Purification Workup Urea-Hydrogen Peroxide Complex (UHP) Trifluoroacetic Anhydride (TFAA) Oxime Preparation Formation of Acylated Oxime
Ballini, Roberto
Marcantoni, Enrico
Petrini, Marino
Reaction of urea-hydrogen peroxide complex with trifluoroacetic anhydride in acetonitrile at 0°C affords in a safe and easy fashion anhydrous solutions of peroxytrifluoroacetic acid. These can be used to oxidize aldoximes to nitroalkanes in good yields. Ketoximes fail to react in these conditions and are cleaved to the parent carbonyl compounds.
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