Synthesis of optically active α,α-distubstituted β-keto esters via chiral β-enamino esters

DOI: 10.1016/S0957-4166(00)82164-3

Source and publish data:

Tetrahedron Asymmetry p. 411 - 414 (1991)

Update date:2022-07-30

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Authors:

Guingant

Hammami Hammami

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Article abstract of DOI:10.1016/S0957-4166(00)82164-3

Michael addition of chiral β-enamino esters to MVK and acrylates promoted by Lewis acids (ZnCl₂, MgBr₂) or high pressure (11-14 Kbar) afforded, after hydrolytic work-up, α,α-disubstituted β-keto esters in good enantiomeric carbon exc

Full text of DOI:10.1016/S0957-4166(00)82164-3

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