Journal of the Chemical Society, Dalton Transactions p. 947 - 953 (1996)
Update date:2022-07-30
Topics:
Boisson, Christophe
Berthet, Jean-Claude
Lance, Monique
Vigner, Julien
Nierlich, Martine
Ephritikhine, Michel
The compounds M[U(cot)(NEt2)3] 1 (cot = η-C8H8, M = Li or K) were prepared by (a) reaction of [U(NEt2)4] or [U(NEt2)3][BPh4] with K2(cot), (b) treatment of UCl4 with LiNEt2 and K2(cot) and (c) reaction of [U(cot)2] with LiNEt2. The compound [U(cot)(NEt2)2(thf)] 2 (thf = tetrahydrofuran) was synthesized by treating [U(NEt2)2Cl2] with K2(cot). Uranium(v) compounds were obtained by oxidation of 1 and 2. Treatment of 1 with TIBPh4 afforded [U(cot)(NEt2)3] which was transformed into [U(cot)(OPri)3] by alcoholysis. Complex 2 reacted with AgBPh4 or Tl(cp) (cp = η-C5H5) to give [U(cot)(NEt2)2(thf)][BPh4] and [U(cot)(cp)(NEt2)2] respectively, the crystal structure of the first of which has been determined.
Anhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Jinan Yijialian Economic and Trade Development Co., Ltd.
Contact:+86 0531-66729596
Address:jinan
Ningbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD
website:http://www.xypharm.com/
Contact:+86-515-84383317
Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
WENZHOU M&C FOREIGN TRADE CO.,LTD.
Contact:+86-577-88862917
Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Doi:10.1002/ardp.19933260802
(1993)Doi:10.1039/c3dt52842a
(2014)Doi:10.1016/j.tetlet.2013.11.113
(2014)Doi:10.1135/cccc19931937
(1993)Doi:10.1021/ja413131m
(2014)Doi:10.1021/ic402767j
(2014)
