From (R)-(+)-pulegone to (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane - A unique spiroacetal from the insect kingdom

DOI: 10.1016/0957-4166(95)00023-I

Source and publish data:

Tetrahedron Asymmetry p. 397 - 400 (1995)

Update date:2022-07-30

Topics:

Authors:

Moore Moore

Kitching

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Article abstract of DOI:10.1016/0957-4166(95)00023-I

Enantioselective syntheses of the unique, insect-derived spiroacetal, (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane and some diastereomers, utilising (R)-(+)-pulegone as chiral source-material, and asymmetric dihydroxylation as a key step, are described.

Full text of DOI:10.1016/0957-4166(95)00023-I

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