Bis(2,6-difluorophenyl)benzoylmethyl cation: α-ketocarbenium ion as a single-electron acceptor

DOI: 10.1016/S0040-4039(00)79718-8

Source and publish data:

Tetrahedron Letters p. 3187 - 3190 (1991)

Update date:2022-09-26

Topics: Electrochemistry Spectroscopy NMR (nuclear magnetic resonance) spectroscopy Nucleophilic substitution reaction

Authors:

Kitagawa

Nishimura Takeuchi

Okamoto Okamoto

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Article abstract of DOI:10.1016/S0040-4039(00)79718-8

The title carbenium ion was observed by low temperature NMR in solution. Its strong oxidizing power was demonstrated by the reduction potential and the effective oxidation of methoxy-substituted benzopinacolone.

Full text of DOI:10.1016/S0040-4039(00)79718-8

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