Synthesis p. 831 - 833 (1987)
Update date:2022-08-03
Topics:
Hoffman, Robert V.
Buntain, Gregory A.
Reaction of a series of aldehydes and ketones with the potassium salt of N,O-bis(trimethylsilyl)hydroxylamine (2) gave high yields of the corresponding oximate anion 5.This anion, formed in a Peterson-type reaction, could be protonated to the oxime 7 or trapped in situ with a variety of electrophiles to give O-substituted oxime derivatives.
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