Heats of protonation of transition-metal complexes: The effect of phosphine basicity on metal basicity in CpIr(CO)(PR3) and Fe(CO)3(PR3)2

DOI: 10.1021/ja00024a026

Source and publish data:

Journal of the American Chemical Society p. 9185 - 9192 (1991)

Update date:2022-08-05

Topics:

Authors:

Sowa Jr., John R.

Zanotti, Valerio

Facchin, Giacomo

Angelici, Robert J.

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Article abstract of DOI:10.1021/ja00024a026

Titration calorimetry has been used to determine the effects of phosphine ligand basicity on the heats of protonation (ΔH_HM) of the metal in the CpIr(CO)(PR₃) and Fe(CO)₃(PR₃)₂complexes (PR_{3
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Full text of DOI:10.1021/ja00024a026

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Product name:{Fe(H)(CO)3(P(CH₃)2C₆H₅)2}⁽¹⁺⁾*CF₃SO₃^(1-)={Fe(H)(CO)3(P(CH₃)2C₆H₅)2}CF₃SO₃

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