S(RN)1 reactions of a tetrasubstituted-1,4-benzoquinone

DOI: 10.1016/S0040-4039(00)79881-9

Source and publish data:

Tetrahedron Letters p. 4125 - 4128 (1991)

Update date:2022-08-05

Topics:

Authors:

Crozet Crozet

Giraud Giraud

Sabuco Sabuco

Vanelle Vanelle

Barreau Barreau

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79881-9

The C-alkylation reaction of 2-chloromethyl-3,5,6-trimethyl-1,4-benzoquinone by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. This mechanism is confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and di-t

Full text of DOI:10.1016/S0040-4039(00)79881-9

Products guided by the article

Product name:2,5-Cyclohexadiene-1,4-dione, 2-[[[bis(1,1-dimethylethyl)amino]oxy]methyl]-3,5,6-trimethyl-

Cas No:136869-45-9

R&D Labs maybe for 136869-45-9

Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China

Relevant to this article

The synthesis and stereochemistry of new 2-substituted 4-thiazolidine acetic acids

Doi:10.1016/S0040-4020(01)96157-5
(1991)
Stepwise mechanism for the bromination of arenes by a hypervalent iodine reagent

Doi:10.1021/acs.joc.9b02784
(2020)
1,3-Dipolar cycloaddition of nitrones with phenylvinyl sulfone. An experimental and theoretical study

Doi:10.1016/j.tetasy.2012.01.006
(2012)
Synthesis and properties of 5,6-dichlorobenzimidazole 2'->5'- and 3'->5'-nucleotide dimers and trimers

Doi:10.1016/0008-6215(92)84178-U
(1991)
Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol

Doi:10.1039/c2dt11752e
(2012)
2-Morpholinoisoflav-3-enes as flexible intermediates in the synthesis of phenoxodiol, isophenoxodiol, equol and analogues: Vasorelaxant properties, estrogen receptor binding and Rho/RhoA kinase pathway inhibition

Doi:10.1016/j.bmc.2012.02.008
(2012)

Article Doi