S(RN)1 reactions of a tetrasubstituted-1,4-benzoquinone

DOI: 10.1016/S0040-4039(00)79881-9

Source and publish data:

Tetrahedron Letters p. 4125 - 4128 (1991)

Update date:2022-08-05

Topics:

Authors:

Crozet Crozet

Giraud Giraud

Sabuco Sabuco

Vanelle Vanelle

Barreau Barreau

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79881-9

The C-alkylation reaction of 2-chloromethyl-3,5,6-trimethyl-1,4-benzoquinone by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. This mechanism is confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and di-t

Full text of DOI:10.1016/S0040-4039(00)79881-9

Products guided by the article

Product name:2,5-Cyclohexadiene-1,4-dione, 2-[[[bis(1,1-dimethylethyl)amino]oxy]methyl]-3,5,6-trimethyl-

Cas No:136869-45-9

R&D Labs maybe for 136869-45-9

SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601

Relevant to this article

The synthesis and stereochemistry of new 2-substituted 4-thiazolidine acetic acids

Doi:10.1016/S0040-4020(01)96157-5
(1991)
Stepwise mechanism for the bromination of arenes by a hypervalent iodine reagent

Doi:10.1021/acs.joc.9b02784
(2020)
1,3-Dipolar cycloaddition of nitrones with phenylvinyl sulfone. An experimental and theoretical study

Doi:10.1016/j.tetasy.2012.01.006
(2012)
Synthesis and properties of 5,6-dichlorobenzimidazole 2'->5'- and 3'->5'-nucleotide dimers and trimers

Doi:10.1016/0008-6215(92)84178-U
(1991)
Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol

Doi:10.1039/c2dt11752e
(2012)
2-Morpholinoisoflav-3-enes as flexible intermediates in the synthesis of phenoxodiol, isophenoxodiol, equol and analogues: Vasorelaxant properties, estrogen receptor binding and Rho/RhoA kinase pathway inhibition

Doi:10.1016/j.bmc.2012.02.008
(2012)

Article Doi