S(RN)1 reactions of a tetrasubstituted-1,4-benzoquinone

DOI: 10.1016/S0040-4039(00)79881-9

Source and publish data:

Tetrahedron Letters p. 4125 - 4128 (1991)

Update date:2022-08-05

Topics:

Authors:

Crozet Crozet

Giraud Giraud

Sabuco Sabuco

Vanelle Vanelle

Barreau Barreau

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Article abstract of DOI:10.1016/S0040-4039(00)79881-9

The C-alkylation reaction of 2-chloromethyl-3,5,6-trimethyl-1,4-benzoquinone by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. This mechanism is confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and di-t

Full text of DOI:10.1016/S0040-4039(00)79881-9

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