Addition of Racemic Alkoxyallylstannanes to an Enantiomerically Pure 2-Methoxyoxazolidine: An Example of Combined Mutual Diastereoface Selection and Kinetic Resolution

DOI: 10.1021/jo00025a001

Source and publish data:

Journal of Organic Chemistry p. 6961 - 6963 (1991)

Update date:2022-08-04

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Authors:

Bernardi, Anna

Poli, Giovanni

Scolastico, Carlo

Zanda, Matteo

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Article abstract of DOI:10.1021/jo00025a001

The BF3*Et2O-promoted addition of racemic α- and γ-alkoxyallylstannanes 2 or 3 to the 2-methoxyoxazolidine 1 afforded adducts 4 and 5 in diastereomeric ratios up to 95:5 accompanied by enantioenriched γ-stannanes (R)-3.This behavior is consistent with a f

Full text of DOI:10.1021/jo00025a001

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