Studies on the Mechanism of Deacetoxy-Deacetylcephalosporin C Synthase using Cyclopropyl Substituted Cephalosporin Probes

DOI: 10.1039/c39910000768

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 768 - 770 (1991)

Update date:2022-08-03

Topics:

Authors:

Baldwin, Jack E.

Adlington, Robert M.

Crouch, Nicholas P.

Keeping, John W.

Leppard, Simon W.

et al. et al.

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Article abstract of DOI:10.1039/c39910000768

Cyclopropyl substituted cephalosporin analogues were prepared and evaluated as substrates for the Fe^II/α-ketoglutarate dependent oxygenase, DAOC-DAC synthase; the first example of catalytic product formation from a cyclopropyl ring cleavage pathway by an α-ketoglutarate dependent oxygenase is reported.

Full text of DOI:10.1039/c39910000768

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