Stealth stereocontrol: Stereochemical reversal of a Michael addition reaction

DOI: 10.1021/ja00026a016

Source and publish data:

Journal of the American Chemical Society p. 9820 - 9824 (1991)

Update date:2022-07-29

Topics:

Authors:

Barrett, Anthony G.M.

Weipert, Paul D.

Dhanak, Dashyant

Husa, Robert K.

Lebold, Suzanne A.

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Article abstract of DOI:10.1021/ja00026a016

The nitroalkene, methyl 5,6-dideoxy-2,3-O-isopropylidene-6-nitro-6-(phenylthio)-β-D-ribo-hex-5(Z)- enofuranoside (1), was found to react with nucleophiles to give, on ozonolysis, the corresponding phenyl thiolesters 3, 5, 6a-c, and 7 bearing the nucleophi

Full text of DOI:10.1021/ja00026a016

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Product name:phenyl (methyl 2,3-O-isopropylidene-5-O-(phenylmethyl)-β-D-allofuranoside)thiouronate

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