A Highly Stereospecific Allylation of Benzil by Using (E)- and (Z)-Allylic Stannanes via Photoinduced Electron Transfer

DOI: 10.1039/c39910001359

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1359 - 1360 (1991)

Update date:2022-08-05

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Authors:

Takuwa, Akio

Nishigaichi, Yutaka

Yamaoka, Takashi

Iihama, Kenji

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Article abstract of DOI:10.1039/c39910001359

Irradiation of benzil in acetonitrile in the presence of (E)- and (Z)-but-2-enyl-, pent-2-enyl-, and hex-2-enyl-tributylstannanes afforded the corresponding (E)- and (Z)-homoallylic alcohols, respectively, with complete retention of the original double bo

Full text of DOI:10.1039/c39910001359

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