ERYTHROSE SESQUI-ACETALS AS ELECTROPHILES. 2-DEOXY-C-NUCLEOSIDES FROM D-GLUCOSE.

DOI: 10.1016/S0040-4039(00)93472-5

Source and publish data:

Tetrahedron Letters p. 4831 - 4834 (1991)

Update date:2022-08-05

Topics:

Authors:

Polt, Robin

Wijayaratne, Thusitha

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Article abstract of DOI:10.1016/S0040-4039(00)93472-5

Cleavage of glucosides with NaIO4 in MeOH furnishes sesqui-acetals (protected dialdehydes).Olefination of these substrates, followed by endocyclic oxymercuration-demercuration furnishes substituted tetrahydrofurans (1,2-dideoxy-1-aryl-D-ribofuranoses).Pro

Full text of DOI:10.1016/S0040-4039(00)93472-5

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