TANDEM /-CYCLOADDITIONS. 2. ASYMMETRIC INDUCTION WITH A CHIRAL VINYL ETHER

DOI: 10.1016/S0040-4020(01)85599-X

Source and publish data:

Tetrahedron p. 4857 - 4876 (1990)

Update date:2022-07-30

Topics:

Authors:

Denmark, Scott E.

Senanayake, C. B. W.

Ho, Ginny-Dai

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Article abstract of DOI:10.1016/S0040-4020(01)85599-X

A tandem <4+2>/<3+2>-cycloaddition of nitroalkenes tethered to α,Sb-unsaturated ester dipolarophiles can be effectively triggered with a vinyl ether.Using the chiral vinyl ether 6 as the dienophile, nitroalkenes 1 and 2 undergo highly selective tandem cyc

Full text of DOI:10.1016/S0040-4020(01)85599-X

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Product name:rac-(1S,3R,5aS,7aS,7bR)-1--7b-methyl-2-oxo-5a,6,7,7a-tetrahydrocyclopenta<1,2,3-gi>pyrrolidino<1,2-a>pyrrolidine

Cas No:137624-82-9

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