Chromium-Carbene-Mediated Synthesis of 4-Oxo β-Lactams (Malonimides) and Malonic Acid Derivatives

DOI: 10.1021/jo00028a013

Source and publish data:

Journal of Organic Chemistry p. 447 - 451 (1992)

Update date:2022-09-26

Topics:

Authors:

Alcaide, Benito

Dominguez, Gema

Plumet, Joaquin

Sierra, Miguel A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00028a013

The photochemical reaction of chromium carbene (Fisher) complexes and readily available iminodithiocarbonates forms 4,4-bis(methylthio) β-lactams in good to excellent yields, and upon N-bromosuccinimide oxidation, these afford 4-oxo β-lactams (malonimides

Full text of DOI:10.1021/jo00028a013

Products guided by the article

Product name:2-Azetidinone, 1-(4-methoxyphenyl)-3-methyl-4,4-bis(methylthio)-3-(phenylmethoxy)-

Cas No:137628-89-8

R&D Labs maybe for 137628-89-8

Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Purestar Chem Enterprise Co.,Ltd

website:http://www.purestarchem.com

Contact:05722157374

Address:no235.huanchengdong Rd
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China

Relevant to this article

Enantioselective synthesis of (+)-3-isorauniticine via a catalytic tandem 'palladium-ene'/carbonylation reaction

Doi:10.1021/ja00025a035
(1991)
Silver and gold complexes with a new 1,10-phenanthroline analogue n-heterocyclic carbene: A combined structural, theoretical, and photophysical study

Doi:10.1002/chem.201200465
(2012)
Selective molecular sequestration with concurrent natural product functionalization and derivatization: From crude natural product extracts to a single natural product derivative in one step

Doi:10.1021/jo201361s
(2011)
Formation of copper(I)-templated [2]rotaxanes using "click" methodology: Influence of the base, the thread and the catalyst

Doi:10.1007/s10847-011-9986-6
(2011)
Transforming terpene-derived aldehydes into 1,2-epoxides via asymmetric α-chlorination: Subsequent epoxide opening with carbon nucleophiles

Doi:10.1039/c1cc15173h
(2011)
End functionalised liquid crystalline bent-core molecules and first DAB derived dendrimers with banana shaped mesogenic units

Doi:10.1039/b415910a
(2005)

Article Doi