Silylphosphinites and their complexation to manganese. Crystal structure of cis-MnBr(CO)4

Article abstract of DOI:10.1016/0022-328X(91)86173-N

The new silylphosphinites, (4-CH3C6H4)2POSiMe3(L) and <(4-CH3C6H4)2PO>2SiMe2(L-L) have been synthesised along with the manganese complexes cis-MnBr(CO)4L, trans,mer-MnBr(CO)3L2 and fac-MnBr(CO)3(L-L).The results of a single crystal X-ray diffraction study