Novel generation of azomethine ylide from N-(α-silylbenzyl)amide by silicon shift: An equivalent of nitrile ylide

DOI: 10.1016/S0040-4039(00)93562-7

Source and publish data:

Tetrahedron Letters p. 5813 - 5816 (1991)

Update date:2022-08-04

Topics:

Authors:

Ohno Ohno

Komatsu Komatsu

Miyata Miyata

Ohshiro Ohshiro

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Article abstract of DOI:10.1016/S0040-4039(00)93562-7

Azomethine ylides were generated from N-(α-silylbenzyl)amides by thermal silicon shift to the oxygen and trapped with dipolarophiles to give the same products as those from the corresponding nitrile ylides via elimination of silanol.

Full text of DOI:10.1016/S0040-4039(00)93562-7

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