Towards the total synthesis of clerodin. Part I

DOI: 10.1016/S0040-4039(00)79435-4

Source and publish data:

Tetrahedron Letters p. 5953 - 5956 (1991)

Update date:2022-08-03

Topics: Retrosynthetic analysis Purification and characterization Scale-up Synthesis of Key Intermediates Safety and Ethical Considerations Optimization and Yield Improvement

Authors:

Bouchard

Renard Renard

Lallemand

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Article abstract of DOI:10.1016/S0040-4039(00)79435-4

A highly stereo- and enantioselective approach to clerodin 1, an insect antifeedant, is described. The key step involved the stereospecific formation of the C₉-C₁₁ bond, at an early stage of the synthesis, using a Claisen rearrangement.

Full text of DOI:10.1016/S0040-4039(00)79435-4

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