Tetrahedron Letters p. 5953 - 5956 (1991)
Update date:2022-08-03
Topics: Retrosynthetic analysis Purification and characterization Scale-up Synthesis of Key Intermediates Safety and Ethical Considerations Optimization and Yield Improvement
Bouchard
Renard
Lallemand
A highly stereo- and enantioselective approach to clerodin 1, an insect antifeedant, is described. The key step involved the stereospecific formation of the C9-C11 bond, at an early stage of the synthesis, using a Claisen rearrangement.
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